This is Dr Mrs The Monarch from The Venture Bros.on Cartoon Network's Adult Swim, I'm not familiar with this character but this sounds like a pretty fun series. I wish I had more time to give this more thought.
wow this is definitely one of the best Dr Mrs The Monarch I've seen on DA. simply gorgeous. It would benefit your funny bone if you got more familiar with Dr. Girlfriend/Dr. Fiancée/ Dr. Mrs. The Monarch lol but yeah AMAZING!